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Á¦¸ñ Removal of iodine (I− and IO3−) from aqueous solutions using CoAl and NiAl layered double hydroxides (2021)

Removal of iodine (I− and IO3−) from aqueous solutions using CoAl and NiAl layered double hydroxides (2021)

 

Jaehyuk Kang, Ferdinan Cintron-Colon, Hyojoo Kim, Jueun Kim, Tamas Varga, Yingge Du, Odeta Qafoku, Wooyong Um, Tatiana G. Levitskaia

 

 

Chemical Engineering Journal

 

Volume 430, Part 1, 15 February 2022, 132788

 

https://doi.org/10.1016/j.cej.2021.132788

 

Received 6 August 2021; Received in revised form 23 September 2021; Accepted 30 September 2021

Available online 5 October 2021

1385-8947/© 2021 Elsevier B.V. All rights reserved.

 

 

Abstract

 

The treatment of radioactive iodine released from nuclear power plants and radiological waste disposal sites is of great concern due to its high mobility and toxicity. In particular, iodide (I−) and iodate (IO3−) are the major iodine species of concern under various pHs and groundwater conditions. Herein, CoAl and NiAl layered double hydroxides (LDHs) were synthesized and investigated to identify the iodine removal mechanism and efficiency. Both CoAl and NiAl LDHs exhibited rapid iodine removal processes within 20 min, following the pseudo-second-order model via ion-exchange with parent NO3− anion in the LDHs. The CoAl LDH¡¯s maximum sorption capacities for I− and IO3− were about 1.67 and 2.16 mmol g−1, respectively, whereas for the NiAl LDH, these were about 2.10 and 2.26 mmol g−1, and they followed the Langmuir isotherm model. Interestingly, both the CoAl and NiAl LDHs showed a preferential ion-exchange affinity for IO3− over I−, which was attributed to the structural similarity of the IO3− and NO3− as well as new formation of secondary Co(IO3)2¡¤2H2O or Ni(IO3)2¡¤2H2O phases. In addition, a desorption study indicated that the selectivity order was SO42− ¡Ã IO3− ¡Ã OH− > HCO3− > Cl− > NO3− ¡Ã I− and demonstrated the higher retention of the IO3− than I− anion. This study provides insights into promising iodine sorbents and the different removal mechanisms of I− and IO3− using CoAl and NiAl LDHs.



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